Diagenetic and post-diagenetic fabrics in the Kamarposht fluorite mine (east of Mazandaran province): Explainaton and genetic interpretation

Document Type : Research Article

Authors

• Faezeh Nabiloo
• Behnam Shafiei Bafti
• Arash Amini

Golestan

10.22067/econg.v9i2.37740

Abstract

Introduction
Upper part of Elika Formation (middle Triassic) in the central Alborz as one of the most important fluorite districts in Iran is the host of some carbonate rock-hosted fluorite deposits such as Kamarposht, Pachi-Miana, Shashroodbar, Era (Alirezaee, 1989; Gorjizad, 1996; Rastad and Shariatmadar, 2001; Rajabi et al., 2013; Vahabzadeh et al., 2013; Zabihitabar and Shafiei, 2015). One of the main active fluorite mines in the central Alborz is Kamarposht which is located at the southeast of DoAb in the Mazandaran province. The Kamarposht mine has 75000 tons of ores and mining there has begun in 2005. The effects and evidences of underground mining in the northern and southern parts of this mine indicate high-grade and coarse-grained ore zones which have fluorite, galena and barite. Until now, basic economic geology studies in the Kamarposht mine including mineralogy, fabric and texture of mineralization for introducing a new fluorite mine in Iran have not been carried out. The present study is based on field observations and macroscopic as well as microscopic studies aimed at identification of morphology and mode of occurrence of the ore body, mineralogy and fabric of mineralization and discussion of as well as presentation of a new genetic model for the Kamarposht mine.

Materials and methods
For the present research study, field geology and sampling were carried out to collect 100 samples from various fluorite ore-types and carbonate host rocks. The samples prepared for thin section (n=55) and polished-thin sections (n=22).

Results
Field observations indicate that economic mineable ore zones of the Kamarposht mine are mainly hosted by dolomitic limestone and silicified carbonate horizons of the Elika Formation. The ore zones have fluorite, barite and galena which are mainly located in fractured and faulted zones as well as karstic cavities in the host horizons. Coarse grain and euhedral fluorites with various colors, significant presence of barite as massive and vein, abundant galena and near contact between mineralization zones in carbonate host rocks (Elika Fm.) and pyrite-bearing coalified shales (base of Shemshak Fm.?) as faulted and/or interbedded are all distinctive geological features for the Kamarposht mine. Fluorite mainly occurs as interrupted, dense and voluminous massive bodies with/without galena which have occupied cavities and open spaces between brecciated fragments of dolomitic limestone relative to the form of disseminate grains, veinlets and geode. Massive and voluminous accumulations of barite in dissolution and karstic cavities and also as discordant veins relative to the bedding of the host rock which have been generated radial, breccias and zebra structures in barite ores. Galena occurs as veinlets and breccias with medium to coarse grain size with/without fluorite in dolomitic and silicified host rocks and also as vein-veinlets into and/or rime of massive barites.
Discussion
Based on field evidences and mode occurrence of ore minerals and ore textures, mineralization in the Kamaposht mine has occurred as syn-diagenetic (primary) and post-diagenetic/epigenetic (main) fabrics. Ores with disseminate particles of ore minerals, stylolite, geode and tiny veinlets fabrics have been interpreted as primary textures that co-exist with diagenesis of host rocks. These fabrics have been formed under diagenetic processes such as nucleation, re-crystalization and disolution of host rocks by diagenetic phreatic reactions that have caused increasing temperature-pressure due to increasing depth of burial diagenesis (Force et al., 1991; Fontbote and Gorzawski 1990; Rastad and Shariatmadar, 2001; Haeri-Ardakani et al., 2013). The main textures of mineralization in the Kamarposht mine namely open-space filling fabrics including veins and breccias fabrics with replacement, network and zebra textures which are associated with dolomitized and silicified host rock have been caused by late and/or post-diagenetic processes (Fontbote and Gorzawski 1990; Sangster, 1996; Leach et al., 2005). Change and conversion of diagenetic mineralization fabrics to epigenetic ones which is associated with developing and increasing the intensity of fluorite-barite-galena mineralization, is attributed to the function of hydrothermal solutions/basianl brines generated due to the main Cimerian orogeny (Rajabi et al., 2013). The increasing dissolution of host rock along with its dolomitization and silicification were probably the main processes responsible for epigenetic mineralization in the Kamarposht mine. Finally, the present study shows that the Kamarposht mine is a fluorite-rich MVT deposit with poly-genetic origin.

References
Alirezaee, S., 1989. Contribution to stratigraphy and mode of generation of F-Pb-Ba deposits in Triassic of eastern Alborz. M.Sc. Thesis, Tehran University, Tehran, Iran, 87 pp. (in Persian with English abstract).
Fontbote, L. and Gorzawski, H., 1990. Genesis of the Mississippi Valley-Type Zn-Pb Deposit of San Vicente, Central Peru: Geologic and Isotopic (Sr, O, C, S, Pb) Evidence. Economic Geology, 85(7): 1402-1437
Force, E.R., Eidel, J.J. and Maynard, J.B., 1991. Sedimentary and diagenetic mineral deposits: A basin analysis approach to exploration. Society of Economic Geologist Publication, Reviews in Economic Geology 5 , USA, 217 pp.
Gorjizad, H., 1996. Study on geology, mineralogy, facies analysis and genesis of Pachi Miana fluorite deposit. M.Sc. Thesis, Tarbiat Modaress University, Tehran, Iran, 156 pp. (in Persian with English abstract)
Haeri-Ardakani, O., Al-Asem, I., Coniglio,M. and Samson, I., 2013. Diagenetic evolution and associated mineralization in Middle Devonian carbonates, southwestern Ontario, Canada. Bulletin of Canadian Petroleum Geology, 61(1): 41–58.
Leach, D., Sangster, D., Kelley, K., Large, R., Garven, G., Allen, C., Gutzmer, J. and Walters, S., 2005. Sediment- hosted lead-zinc deposits: a global perspective. In: J. Hedenquist, J. Thompson, R. Goldfarb, and J. Richards, (Editors), 100th Anniversary Volume of Economic Geology, Society of Economic Geologist Publication, USA, pp. 561-607.
Rajabi, A., Rastad, E. and Canet, C., 2013. Metallogeny of Permian-Triassic carbonate-hosted Zn-Pb and F deposits of Iran: A review for future mineral exploration. Australian Journal of Earth Sciences, 60(2): 197-216.
Rastad, E. and Shariatmadar, A., 2001. Sheshroodbar fluorite deposits, sedimentary and diagenetic fabrics and its depositional environment (Savad Kuh, Mazandaran province). Journal of Geosciences, 10(41-42): Sangster, D.F., 1996. Carbonate-hosted lead-zinc deposits. Society of Economic Geology, Special Publication No.4, 664 pp.
Vahabzadeh, G., Khakzad, A., Rasa, I.‌ and Mosavi, M.R., 2014. Fluorite REEs geochemistry in fluorite deposits of central Alborz. New Finds of Applied Geology, 16(1): 58-70. (in Persian with English abstract)
Zabihitabar, Sh. and Shafiei, B., 2015. Mineralogy and mode occurrence of sulfides, sulfates and carbonates at fluorite mines in East of Mazandaran province. Iranian Journal of Geology, 33(1): 62-78. (in Persian with English abstract)

Keywords

• The Kamarposht mine
• Fluorite
• Elika Formation
• Mazandaran

20.1001.1.20087306.1396.9.2.12.0

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References

Alirezaee, S., 1989. Contribution to stratigraphy and mode of generation of F-Pb-Ba deposits in Triassic of eastern Alborz. M.Sc. Thesis, Tehran University, Tehran, Iran, 87 pp. (in Persian with English abstract).

Berberian, M. and King, G.C.P., 1981. Towards a paleogeography and tectonic evolution of Iran. Canadian Journal of Earth Sciences, 18(2): 210-265

Brunet, M.F., Wilmsen, M. and Granath, J.W., 2009. South Caspian to Central Iran basin. Geological Society, Special Publications, 312, London, 352 pp.

Craige, J.R. and Vaughan, D.J., 1981. Ore microscopy and ore petrography. John Wiley & Sons Incorporated, USA, 851 pp.

Fisher, J., Lillie, R. and Rakovan, J., 2013. Flourite in Mississippi Valley-Type Deposits. Rocks & Minerals, 88(1): 20-47.

Fontbote, L., 1981. Stratabound Pb-Zn-F-Ba deposits in carbonate rocks: New aspects of Paleogeographic location. Facies factors and diagenetic evolution (with a comparison of occurrence from the Triassic of southern Spain, The Triassic Liassic of central Peru and other localities). Ph.D. Thesis, Heidelberg University, Hidelberg, Germany, 193 pp.

Fontbote, L. and Gorzawski, H., 1990. Genesis of the Mississippi Valley-Type Zn-Pb Deposit of San Vicente, Central Peru: Geologic and Isotopic (Sr, O, C, S, Pb) Evidence. Economic Geology, 85(7): 1402-1437

Force, E.R., Eidel, J.J. and Maynard, J.B., 1991. Sedimentary and diagenetic mineral deposits: A basin analysis approach to exploration. Society of Economic Geologist Publication, Reviews in Economic Geology 5 , USA, 217 pp.

Gaetani, M., Angiolini, L., Ueno, K., Nicora, A., Stephenson, M.H., sciunnach, D., Rettori, R., Price, G.D. and Sabouri, J.,2009. Pennsylvanian–Early Triassic stratigraphy in the Alborz Mountains(Iran). In: M.F Brunet, M. Wilmsen, and J.W. Granath, (Editors), South Caspian to Central Iran basin. Geological Society, Special Publications 312, London, pp.79–128.

Gorjizad, H., 1996. Study on geology, mineralogy, facies analysis and genesis of Pachi Miana fluorite deposit. M.Sc. Thesis, Tarbiat Modaress University, Tehran, Iran, 156 pp. (in Persian with English abstract)

Guilbert, J.M. and Park, Ch.F., 1997. The geology of ore deposits. Freeman and Company, New York, 985 pp.

Haeri-Ardakani, O., Al-Asem, I., Coniglio,M. and Samson, I., 2013. Diagenetic evolution and associated mineralization in Middle Devonian carbonates, southwestern Ontario, Canada. Bulletin of Canadian Petroleum Geology, 61(1): 41–58.

Hall, W.E. and Heyl, A.V., 1968. Distribution of minor elements in ore and host rock, Illinois-Kentucky fluorite district and Upper Mississippi-Valley Zinc-lead district. Economic Geology, 63(4): 655-670.

Jazi, M.A. and Shahabpour, J., 2010. Study on mineralogical, fabric, textural and geochemical characteristics of Nakhlak Pb mine, Esfahan, Iran. Journal of Economic Geology, 2(2): 131-151. (in Persian with English abstract)

Kendrick, M.A., Burgess, R.A., Pattrick, D. and Turner, G., 2002. Hydrothermal fluid origins in a fluorite-rich Mississippi Valley–type district: Combined noble gas (He, Ar, Kr) and halogen (Cl,Br, I): Analysis of fluid inclusions from the South Pennine ore field, United Kingdom. Economic Geology, 97(3): 435-451.

Kesler, S.E., 1977. Geochemistry of Manto Fluorite Deposits, Northern Coahuila, Mexico. Economic Geology, 72(2): 204-218.

Lasemi, Y., Jahani, D. and Kohansal Ghadimvand, N., 2000. Study on Elika formation in west of central Alborz (Ghoznavi area): facies, sedimentary environment and sequence stratigraphy. 4th Congress of Geological Society of Iran, University of Tehran, Tehran, Iran. (in Persian with English abstract)

Lasemi, Y., Lotfpour, M. and Tahmasebi, A., 1997. Microfacies, sedimentary environment reconstruction and stratigraphy sequence of Elika formation in East of central Alborz (Shahmirzad area). 1th Congress of Geological Society of Iran, University of Tehran, Tehran, Iran. (in Persian with English abstract)

Leach, D., Sangster, D., Kelley, K., Large, R., Garven, G., Allen, C., Gutzmer, J. and Walters, S., 2005. Sediment- hosted lead-zinc deposits: a global perspective. In: J. Hedenquist, J. Thompson, R. Goldfarb, and J. Richards, (Editors), 100th Anniversary Volume of Economic Geology, Society of Economic Geologist Publication, USA, pp. 561-607.

Mehraban, Z., 2013. REEs geochemistry in fluorite deposits of Elika Formation (East of Mazandaran Province). M.Sc Thesis, Golestan University, Gorgan, Iran, 93 pp. (in Persian with English abstract)

Mehraban, Z., Shafiei, B. and Shamanian, G.H., 2016. Rare Earths in fluorite deposits of Elika Formation (East of Mazandaran Province). Journal of Economic Geology, 8 (1): 201-221. (in Persian with English abstract)

Nordstrom, D.K. and Jenne, E.A., 1977. Fluorite solubility equilibria in selected geothermal waters. Geochimica et Cosmochimica Acta, 41(1): 175 188.

Rajabi, A., Rastad, E. and Canet, C., 2013. Metallogeny of Permian-Triassic carbonate-hosted Zn-Pb and F deposits of Iran: A review for future mineral exploration. Australian Journal of Earth Sciences, 60(2): 197-216.

Rastad, E. and Shariatmadar, A., 2001. Sheshroodbar fluorite deposits, sedimentary and diagenetic fabrics and its depositional environment (Savad Kuh, Mazandaran province). Journal of Geosciences, 10(41-42): 20-38. (in Persian with English abstract)

Robb, L.J., 2005. Introduction to ore-forming processes. Blackwell Science, USA, 373 pp.

Ruiz, J., Kesler, S.E., Jones, L.M. and Sutter, J.F., 1980. Geology and geochemistry of the Las Cuevas fluorite deposit, San LuisPotosi, Mexico. Economic Geology, 75(8): 1200–1209.

Sangster, D.F., 1996. Carbonate-hosted lead-zinc deposits. Society of Economic Geology, Special Publication No.4, 664 pp.

Schneider, H.J., Moller, P., Parekh, P.P. and Zimmer, E., 1977. Fluorine contents in carbonate sequences and rare earths distribution in fluorites of Pb-Zn deposits in East-Alpine Mid-Triassic. Mineralium Deposita, 12(1): 22-36.

Sefidian, S., 2014. Geology and mineralogy of Era fluorite mine, southeast of Kiasar, Mazandaran province. M.Sc. Thesis, Golestan University, Gorgan, Iran, 72 pp. (in Persian with English abstract)

Shariatmadar, A., 1999. Geology and genesis of Sheshrodbar fluorite deposit. M.Sc. Thesis, Tarbiat Modaress University, Tehran, Iran, 230 pp. (in Persian with English abstract)

Tabasi, H., 1997. Structural analysis of Sheshroodbar fluorite mine. M.Sc. Thesis, Tarbiat Modaress University, Tehran, Iran, 130 pp. (in Persian with English abstract)

Tadaion, M., Mohajel. M. and Rashidnejad Omran, N., 2014. Structural and mineralization analysis of Fluorite in eastern Alborz. Procceding of 32th National and 1th International Geosciences Congress, Geological Survey of Iran, Tehran, Iran. (in Persian with English abstract)

Vahabzadeh, G., Khakzad, A., Rasa, I.‌ and Mosavi, M.R., 2008. Oxygen and carbon isotopes and REE study in the Emaft fluorite mine, Savad Kuh region (Mazandaran province). Research Journal of Isfahan University, 29(3): 189-200. (in Persian with English abstract)

Vahabzadeh, G., Khakzad, A., Rasa, I.‌ and Mosavi, M.R., 2009. Study on S isotopes in galena and barite of Savad Kuh fluorite deposits. Journal of Sciences, Islamic Azad University, 69(18): 99-108. (in Persian with English abstract)

Vahabzadeh, G., Khakzad, A., Rasa, I.‌ and Mosavi, M.R., 2014. Fluorite REEs geochemistry in fluorite deposits of central Alborz. New Finds of Applied Geology, 16(1): 58-70. (in Persian with English abstract)

Vahdati Daneshmand, F., 1985. New data about the upper boundary of Elika formation and introducing the Paland deposits. Geological Survey of Iran, Tehran, Internal Report, 17 pp.

Vahdati Daneshmand, F. and Saeidi, A., 1991. Geological map of Sari scale 1:250000. Geological Survey of Iran.

Wilmsen, M., Fursich, F.T., Seyed-Emami, K., Majidifard, M.R. and Taheri, J., 2009. The Cimmerian orogeny in northern Iran: tectono-stratigraphic evidence from the foreland .Tera Nova, 21‌(3): 211-218.

Zabihitabar, Sh., 2013. Stable isotope study in fluorite mines of SawadKuh region, Mazandaran province. M.Sc Thesis, Golestan University, Gorgan, Iran, 117 pp, (in Persian with English abstract)

Zabihitabar, Sh. and Shafiei, B., 2015. Mineralogy and mode occurrence of sulfides, sulfates and carbonates at fluorite mines in East of Mazandaran province. Iranian Journal of Geology, 33(1): 62-78. (in Persian with English abstract)