@article { author = {Jazi, Mohammad Ali and Karimpour, Mohammad Hassan and Malekzadeh Shafaroudi, Azadeh}, title = {Mineralization, geochemistry, fluid inclusion and sulfur stable isotope studies in the carbonate hosted Baqoroq Cu-Zn-As deposit (NE Anarak)}, journal = {Journal of Economic Geology}, volume = {7}, number = {2}, pages = {179-202}, year = {2015}, publisher = {Ferdowsi University of Mashhad}, issn = {2008-7306}, eissn = {2423-5865}, doi = {10.22067/econg.v7i2.46069}, abstract = {Introduction The Baqoroq Cu-Zn-As deposit is located northeast of the town ofAnarak in Isfahan province, in theeast central areaof Iran. Copper mineralization occursin upper cretaceous carbonate rocks.Studyof thegeologyof the Nakhlak area, the location ofa carbonate-hosted base metaldeposit, indicatesthe importance of stratigraphic, lithological and structural controls in the placement of this ore deposit. (Jazi et al., 2015).Some of the most world’s most important epigenetic, stratabound and discordant copperdeposits are the carbonate hosted Tsumeb and Kipushi type deposits,located in Africa. The Baqoroq deposit is believed to be of this type. Materials and methods In the current study, fifty rock samples were collected from old tunnels and surface mineralization. Twenty-two thin sections, ten polished sections and four thin-polished sections were prepared for microscopic study. Ten samples were selected for elemental analysis by ICP-OES (Inductively coupled plasma optical emission spectrometry) by the Zar Azma Company (Tehran) and AAS (Atomic absorption spectrometry) at the Ferdowsi University of Mashhad. Seven doubly polished sections of barite mineralization were prepared for microthermometric analysis. Homogenization and last ice-melting temperatures were measured using a Linkam THMSG 600 combined heating and freezing stage at Ferdowsi University of Mashhad. Sulfur isotopes of five barite samples were determined by the Iso-Analytical Ltd. Company of the UK. The isotopic ratios are presented in per mil (‰)notation relative to the Canyon Diablo Troilite. Results The upper Cretaceoushost rocks of the Baqoroq deposit include limestone, sandstone, and conglomerate units. Mineralization is controlled by two main factors: lithostratigraphy and structure. Epigenetic Cu-Zn mineralizationoccurs in ore zones as stratabound barite and barite-calcite veins and minor disseminated mineralization. Open space filling occurred as breccia matrix, crustification banding,andbotryoidaltexture. The host rock has undergone dolomitization alteration Hypogene minerals include chalcopyrite, pyrite, sphalerite, galena, enargite, barite, and calcite. Supergene minerals include malachite, azurite, covellite, chrysocolla, chalcocite, cerussite, smithsonite, native copper and iron oxide minerals. Sulfantimonides and sulfardenides are abundant in low- and moderate temperature stages of the deposit, while bismuth sulfides generally occur in higher temperature ores, according to Malakhov, 1968. Analysis of rich ore samples indicates copper is the most abundant heavy metal in the ore (average 20.28 wt%), followed by zinc (average ~ 1 wt%) and arsenic (average ~ 1 wt%), respectively. Thepresence of many trace elements in the ore, such as Sb, Pb, Ag and V, are very important. Element pairs such as Ag-Cu, Zn-Cd, Zn-Sb, Fe-V and Pb-Mo are correlated with each other. The Baqoroq ore minerals are rich in As, Sb and poor in Bi. Highamountsof antimony usually occur in a low temperature stage (Marshall and Joensuu, 1961). Malakhov (1968) suggested thata high Sb/Biratio in the ore indicates a low temperature of formation for the Baqoroq deposit. Sulfide mineralization fluids were found to have homogenization temperatures between 259 and 354°C and salinities between 8.37 and 13.18 wt% NaCl eq. Surface water apparently diluted theore-bearing fluids in the final stages and deposited sulfide-freecalcite veins at relatively low temperatures (78 to 112 °C) and low salinities (3.59 to 6.07 wt% NaCl eq.). The δ34S values of barite of the Baqoroq deposit range from +13.1 to +14.37‰from whichδ34S values of ore fluids were calculated to vary between -8.57‰ and -7.23‰. Sulfur within natural environments is derived ultimately from either igneous or seawater sources (Ohmoto and Rye, 1979). Barite δ34S values of Baqoroq deposit lie within the range of Cretaceous-age oceanic sulfate values. The reduction of sulfate to sulfide couldhave been caused either by bacterial sulfate reduction or by nonbacterial sulfate reduction through a reaction with organic materialin the sedimentary rocks (thermochemical sulfate reduction). However, the narrow range of δ34S and positive values indicates that they were not produced by bacterial sulfate reduction.Partial thermochemical reduction of sulfates has apparently produced light sulfurvalues (~ 21‰ lighter) and it has been effective inthe deposition of ore minerals. Organic matter occurs as graphite in the Baqoroq formation in proximity of Baqoroq deposit (Cherepovsky et al., 1982). Discussion Epigenetic, stratabound and discordant Cu-Zn-As mineralization in the Baqoroq deposit occurs as open space filling of upper Cretaceous rocks. Host rock is partially dolomitized by ascending warm, saline fluids. Seawater sulfates were the source of the sulfidesulfur and the sulfate in the barite. The reduced sulfur was generated by partial thermochemical reduction and it was effective inthe deposition ofthe ore minerals. Based onthe evidence of carbonate host rocks, the absence of igneous activity, the open space filling texture, mineralogy, dolomite alteration, ore geochemistry (As and Sb high content and absence of Bi), microthermometric data of ore bearing fluid and sulfur isotope values, the Baqoroq deposit is very similar to the carbonate hosted copper deposits in Africa and in particular the Tsumeb deposit in Namibia. The Baqoroqdepositmay have been produced bymetamorphicfluids during orogenyrelated to theclosureof the Neo-Tethys ocean. References Cherepovsky, N., Plyaskin, V., Zhitinev, N., Kokorin, Y., Susov, M., Melnikov, B. and Aistov, L., 1982. Report on detailed geological prospecting in Anarak area (Central Iran) Nakhlak locality. Geological Survey of Iran and Technoexport Company, Tehran. Report 14, 196 pp. Jazi, M.A., Karimpour, M.H., Malekzadeh, A. and Rahimi, B., 2015. Stratigraphic, lithological and structural controls in placement of Nakhlak deposit (northeast of Esfahan). Advanced Applied Geology, 15(1): 59-75. (in Persian with English abstract) Malakhov, A.A., 1968. Bismuth and antimony in galena as indicators of some conditions of ore formation. Geochemistry International, 7(11): 1055-1068. Marshall, R.R. and Joensuu, O., 1961. Crystal habit and trace element content of some galena. Economic Geology, 56(4): 758-771. Ohmoto, H. and Rye, R.O., 1979. Isotopes of sulphur and carbon. In: H.L. Barnes (Editor), Geochemistry of Hydrothermal Ore Deposits. Wiley-Interscience, New York, pp. 509-567.}, keywords = {copper,fluid inclusions,Sulfur isotopes Baqoroq,Anarak}, title_fa = {مطالعات کانی‌ سازی، ژئوشیمی، سیالات ‌درگیر و ایزوتوپ پایدار گوگرد کانسار Cu-Zn-As باقرق با سنگ میزبان کربناته (شمال‌ شرق انارک)}, abstract_fa = {کانسار Cu-Zn-As باقرق در شمال شرق شهر انارک و در استان اصفهان قرار دارد. کانی‌سازی به‌صورت دیرزاد، ماهیت چینه‌کران و بافت و ساخت پرکننده فضای خالی در سنگ میزبان کربناتی رخداده است. کانی‌شناسی بخش درون‌زاد شامل کالکوسیت، کالکوپیریت، پیریت، اسفالریت، گالن، انارژیت، باریت و کلسیت و کانیهای بخش برون‌زاد شامل مالاکیت، آزوریت، کوولیت، کریزوکولا، کالکوسیت، سروزیت، اسمیت‌زونیت، مس طبیعی، هماتیت، گوتیت و لیمونیت می‌باشد. سنگ میزبان کربناتی در اطراف زون‌های کانه‌دار متحمل دگرسانیهای دولومیتی‌شدن و کلسیتی‌شدن شده است. مس به‌عنوان عنصر اصلی ذخیره (با میانگین 28/20 درصد وزنی) و پس از آن عناصر روی (با میانگین تقریبی 1 درصد وزنی) و آرسنیک (با میانگین تقریبی 1 درصد وزنی) می‌باشند. مطالعات سیالات‌درگیر روی کانی باریت نشان می‌دهد سیال کانه‌دار سولفیدی دارای محدوده دمای همگن شدن بین 259 تا 354 درجه سانتی‌گراد و میزان شوری بین 8 تا 13 درصد وزنی معادل NaCl می‌باشد. سیال کانه‌دار در مراحل پایانی کانی‌سازی با آبهای جوی دچار اختلاط شده و فاز تأخیری غیر سولفیدی کلسیتی با محدوده دمای نسبتاً پایین ‌(78 تا 112 درجه سانتی‌گراد) و درجه شوری پایین (بین 3 تا 6 درصد وزنی معادل NaCl) را تشکیل داده است. محدوده مقادیر 34Sδ کانی‌ باریت کانسار باقرق بین 13+ تا 14+ در هزار بوده در حالی‌که محاسبه مقدار 34Sδ مربوط به سیال کانه‌دار پس از تصحیح دمایی بین 7- تا 8- در هزار به‌دست آمد. منشأ گوگرد باقرق با توجه به شباهت ایزوتوپ باریت با سولفات‌های دریایی کرتاسه، احتمالاً از لایه‌های تبخیری این دوره زمانی تأمین شده است. این سولفا‌ت‌ها توسط فرآیند‌های ترموشیمیایی به‌صورت بخشی به گوگرد احیایی با مقدار ایزوتوپی سبک‌تر (حدود 21 در هزار) تبدیل و جهت ته‌نشست سولفیدها مورد استفاده قرار گرفته است. کانسار باقرق با توجه به خصوصیاتی همچون سنگ میزبان کربناته، غیاب فعالیت آذرین، بافت پرکننده فضای خالی، دگرسانی دولومیتی،کانی‌شناسی، ژئوشیمی ماده‌معدنی (وجود As و Sb بالا و عدم حضور Bi)، داده‌های دماسنجی و مقادیر ایزوتوپ گوگرد، شباهت زیادی با کانسارهای مس با سنگ میزبان کربناته در افریقا و به‌ویژه نوع سومب (Tsumeb) در نامیبیا نشان می‌دهد. کانسار باقرق احتمالاً مرتبط با سیالات دگرگونی آزاد شده در حین فازهای کوه‌زایی مرتبط با بسته‌شدن اقیانوس نئوتتیس می‌باشد.}, keywords_fa = {مس,سنگ میزبان کربناته,سیال درگیر,ایزوتوپ پایدار گوگرد,باقرق}, url = {https://econg.um.ac.ir/article_30724.html}, eprint = {https://econg.um.ac.ir/article_30724_74afd9556ef0dccaed971e0c91db98e1.pdf} }